Activation of periodate by granular activated carbon for acid orange 7 decolorization
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•The GAC/IO4 system showed a remarkable synergistic effect for AO7 decolorization.

•Iodyl radical was speculated to be the dominating reactive species in the system.

•The dried-GAC exhibited excellent catalytic ability and sustained reuse capability.

•Contributor to the enhancement of AO7 removal with the dried-GAC was testified.

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