文摘
In order to explore unconventional superconductivity, we have studied pressure effect on a 4d-electron Mott insulator Ca2RuO4. Pressurisation to Ca2RuO4 above 0.5 GPa transforms it from a Mott insulator to a metal with a ferromagnetic ground state. The itinerancy of the ferromagnetic state at 2 GPa is quantitatively evidenced by the magnetisation process at 2 K. Moreover, the pressure phase diagram of this system suggests the existence of a ferromagnetic quantum phase transition at 10 GPa.