A Pd-metalated porous organic polymer as a highly efficient heterogeneous catalyst for C-C couplings

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• 作者：Zhifeng Dai ; Fang Chen ; Qi Sun ; Yanyan Ji ; Liang Wang ; Xiangju Meng ; ^{mengxj@zju.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Feng-Shou Xiao
• 关键词：Porous organic polymer ; Phenanthroline ligand ; Carbon&ndash ; carbon couplings ; Pd-based heterogeneous catalyst
• 刊名：Chinese Journal of Catalysis
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：37
• 期：1
• 页码：54-60
• 全文大小：2370 K

文摘

An efficient catalyst system based on a Pd-metalated porous organic polymer bearing phenanthroline ligands was designed and synthesized. This catalyst was applied to various C–C bond-forming reactions, including the Suzuki, Heck and Sonogashira couplings, and afforded the corresponding products while exhibiting excellent activities and selectivities. More importantly, this catalyst can be readily recycled. These features show that such catalysts have significant potential applications in the future.