In-situ TiN/Ti3Al composite coating was synthesized on Ti6Al4V alloy by laser cladding.
The influence of Ti and AlN molar ratio on the microstructure of the coating was studied.
The TiN/Ti3Al intermetallic coating is mainly composed of α-Ti, TiN and Ti3Al phases.
The relative oxidation resistance of the coating at 600 °C and 800 °C is 6.83 and 1.94.
The microhardness of the coating reaches 844HV0.2, 3.4 times higher than the bare substrate.