Chemoselective hydrogenation of functionalized nitroarenes using MOF-derived co-based catalysts
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- 作者：Xi Wang ; Yingwei Li ; liyw@scut.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Heterogeneous catalysis ; Cobalt ; Metal-organic frameworks ; Amines ; Hydrogenation
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：August 2016
- 年：2016
- 卷：420
- 期：Complete
- 页码：56-65
- 全文大小：2205 K
文摘
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Co/C–N was prepared by simple pyrolysis of MOFs.
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Nitroarenes are converted to anilines with other reducing groups remaining intact.
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Co-N centers present in the catalyst lead to the unique chemoselectivity.
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The reaction showed a first-order dependence on H2 pressure.