Mechanical properties and in vitro degradation of electrospun bio-nanocomposite mats from PLA and cellulose nanocrystals

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• 作者：Qingfeng Shi ; Chengjun Zhou ; Yiying Yue ; Weihong Guo ; Yiqiang Wu ; Qinglin Wu
• 关键词：Electrospinning ; Cellulose nanocrystals ; Nanocomposites ; Poly(lactic acid) (PLA) ; In vitro degradation
• 刊名：Carbohydrate Polymers
• 出版年：2012
• 出版时间：1 September, 2012
• 年：2012
• 卷：90
• 期：1
• 页码：301-308
• 全文大小：1556 K

文摘

Fibrous bio-nanocomposite mats consisting of cellulose nanocrystals (CNCs) and poly(lactic acid) (PLA) were electrospun from a solvent mixture consisting of N,N¡ä-dimethylformamide and chloroform at room temperature. Morphological, mechanical and thermal properties, as well as in vitro degradation of nanocomposite mats were characterized as a function of material composition. Average diameter of the electrospun fibers decreased with increased CNC-loading level. Thermal stability, and tensile strength and modulus of nanocomposite mats were effectively improved by the addition of CNCs up to the 5 wt % level. The reinforcement of CNCs on electrospun mats was illustrated by the observation of SEM-based morphologies on the tensile fracturing process of nanocomposite mats. At the CNC content of 5 wt % , the maximum tensile stress and Young's modulus of the nanocomposite mats increased by 5 and 22 folds than those of neat PLA mats, respectively. Moreover, compared with neat PLA mats, the nanocomposite mats, especially at high CNC-loading levels, degraded more rapidly in phosphate-buffered saline solution.