Valence band offset of MgO/InP heterojunction was measured by X-ray photoelectron spectroscopy.
Two sets of core level pairs in the MgO/InP system were used to demonstrate the accuracy of the calculation.
The valence-band and conduction-band offset were 5.33 eV and 1.16 eV for two sets of core level pairs.
Formation of considerable space charge like layer at the interface of MgO/InP heterostructure.