The reduction of nickel from low-grade nickel laterite ore using a solid-state deoxidisation method
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- 作者：Bo ; Li ; Hua ; Wang ; ; ; wanghuaheat@hotmail.com ; Yonggang ; Wei
- 关键词：Nickel laterite ore ; Conversion percentage ; Metallic nickel ; Solid state deoxidisation
- 刊名：Minerals Engineering
- 出版年：2011
- 出版时间：November 2011
- 年：2011
- 卷：24
- 期：14
- 页码：1556-1562
- 全文大小：979 K
文摘
The reduction of nickel from low-grade nickel laterite ore using a solid-state deoxidisation method was studied. The effects of temperature, time, reductant type and CaO content on the conversion percentage of the total nickel to metallic nickel (¦ÁNi) in the nickel laterite ore reduction process were investigated. The results showed that ¦ÁNi was strongly influenced by the reaction temperature in both gas¨Csolid and solid¨Csolid reduction processes, and a higher temperature was more favourable for nickel reduction. Because the reduction mechanism of nickel laterite ore (NiO + CO ?CO2 + Ni) is indirect, a higher ¦ÁNi (>80 % ) can be obtained by increasing the CO and anthracite content. In the gas¨Csolid reduction process, a longer reaction time favoured nickel reduction, and the conversion percentage decreased when a gaseous reductant was used at 850 ¡ãC because of phase transformation. In the solid¨Csolid reduction process, the conversion percentage of the total nickel to metallic nickel first increased and then decreased with increasing reduction time and CaO content. In both reduction processes, taenite was found by XRD in the reduced ore because of iron oxide reduction and metallic nickel formation. SEM revealed that the nickel laterite ore was transformed from large granular and sandwich structures to small granular and flocculent structures during the reduction process.