TiO2/GQDs composites were prepared by a facile one-step hydrothermal method. GQDs were strongly coupled onto the surface of TiO2 nanoparticles by this method. The TiO2/GQDs showed enhanced light absorption and charge separation efficiency. The TiO2/GQDs exhibited higher photocatalytic H2 evolution activity than pure TiO2. GQDs play synergistic roles by acting as both photosensitizer and electron acceptor.