Cloud-point measurement of binary and ternary mixtures for the P(MMA-co-PnFPA) in supercritical fluoric solvents

详细信息    查看全文

• 作者：Hun-Soo Byun ; ^{hsbyun@jnu.ac.kr} ; Chang-Ryung Kim ; Soon-Do Yoon
• 关键词：Dispersion polymerization ; Supercritical carbon dioxide ; P(MMA-co-PnFPA) ; CH2F2 ; CHF3 ; CHClF2 ; High pressure phase behavior ; Cloud-point curves
• 刊名：The Journal of Supercritical Fluids
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：120
• 期：part_P2
• 页码：226-239
• 全文大小：3454 K
• 卷排序：120

文摘

The physicochemical property for the P(MMA-co-PnFPA) using the ratio of MMA vs PnFPA and AIBN content was investigated. Cloud-point data up to 453 K and 220 MPa are reported for the P(MMA-co-PnFPA) in supercritical solvents. Phase behavior for the P(MMA-co-PnFPA) + CH2F2, CHF3 and CHClF2 mixtures are measured in UCST or LCST behavior.