The MWCNT/MnO2/SMPU hybrid film can be changed into various shapes under an external force and maintained them after removing the external force. The MWCNT/MnO2/SMPU hybrid film can be tailored into arbitrarily shapes for required. The MWCNT/MnO2/SMPU hybrid film is a very promising electrode material for assembling supercapacitor with shape-controllable and shape-tailorable property.