Seed-mediated synthesis of dendritic platinum nanostructures with high catalytic activity for aqueous-phase hydrogenation of acetophenone

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• 作者：Yuan Yuan^a ; ^b ; Yusuf Valentino Kaneti^c ; Minsu Liu^d ; Fangzhu Jin^b ; Danielle Frances Kennedy^e ; Xuchuan Jiang^d ; ^{Xuchuan.Jiang@monash.edu" class="auth_mail" title="E-mail the corresponding author} ; Jun Huang^b ; Aibing Yu^c ; ^d
• 关键词：Dendritic Pt nanoparticles ; Aqueous-phase hydrogenation ; Acetophenone conversion ; Seed mediated synthesis
• 刊名：Journal of Energy Chemistry
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：24
• 期：5
• 页码：660-668
• 全文大小：2658 K

文摘

This work reports a facile and efficient seed-mediated method for the synthesis of dendritic platinum (Pt) nanoparticles (NPs) at low temperatures of 55–60 °C in water, using L-ascorbic acid as a reducing agent and sodium citrate as a capping agent.It is found that the dendritic Pt NPs (10–150 nm) are composed of tiny Pt nanocrystals, which nucleate and grow through the introduced smaller Pt seeds with diameters of 3–5 nm. Further investigation shows that the dendritic Pt nanostructures display excellent catalytic performance in an aqueous-phase aromatic ketone hydrogenation reaction, including: (i) acetophenone conversion rate of > 90%, with smaller dendritic Pt NPs (10–46 nm) offering a higher conversion efficiency; (ii) high chemoselectivity toward carbonyl group (90.6%–91.5%), e.g., the selectivity to 1-phenylethanol is ∼90.1% with nearly 100% acetophenone conversion for 10 nm dendritic Pt NPs within 60 min, under mild reaction conditions (20 °C, 1.5 bar H₂ pressure, and 1.5 mol% catalyst). The high catalytic activity, selectivity and stability of the dendritic Pt nanostructures under the organic solvent-free conditions make them promising for many potential applications in green catalytic conversion of hydrophilic biomass derived compounds.