Cobalt catalyzed peroxymonosulfate oxidation of tetrabromobisphenol A: Kinetics, reaction pathways, and formation of brominated by-products
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- 作者：Yuefei Jia ; 1 ; Deyang Kongb ; 1 ; Junhe Lua ; jhlu@njau.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Hao Jina ; Fuxing Kanga ; Xiaoming Yina ; Quansuo Zhoua
- 关键词：Cobalt catalyzed peroxymonosulfate oxidation ; Sulfate radical ; Tetrabromobisphenol A ; Brominated disinfection by-products
- 刊名：Journal of Hazardous Materials
- 出版年：2016
- 出版时间：5 August 2016
- 年：2016
- 卷：313
- 期：Complete
- 页码：229-237
- 全文大小：1736 K
文摘
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Cobalt catalyzed peroxymonosulfate oxidation of tetrabromobisphenol A.
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Phenolic moiety was the reactive site for sulfate radical attack.
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Pathways include β-scission, oxidation, debromination and coupling reactions.
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Brominated disinfection by-products were found during TBBPA degradation.
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Humic acid inhibited TBBPA degradation but promoted DBPs formation.