ABE from model solutions/fermentation broth was salted out by K3PO4.
More than 90 wt% of ABE was recovered and more than 99.75% of water was removed.
Higher solvents level permits the higher recovery of ABE.
ABE solubility in salt solution showed a linear relation with the molality of K3PO4.
Salting-out can reduce the energy consumption for the subsequent distillation.