Microwave-assisted hydrothermal synthesis of NiSx and their promotional effect for the hydrodeoxygenation of p-cresol on MoS2
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- 作者：Weiyan Wanga ; b ; wangweiyan@xtu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Kui Wua ; Lu Lia ; Song Tana ; Guohua Zhua ; Wensong Lia ; Zhiqiang Hea ; Yunquan Yanga ; b ; yangyunquan@xtu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：NiSx ; Phase composition ; Microwave-assisted hydrothermal method ; Hydrodeoxygenation ; MoS2 ; Remote Control model
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：10 January 2016
- 年：2016
- 卷：74
- 期：Complete
- 页码：60-64
- 全文大小：827 K
文摘
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NiSx with different phase compositions were synthesized by the microwave-assisted hydrothermal method.
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The phase composition of NiSx was controlled by adjusting the synthesis conditions.
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The presence of NiS2 enhanced p-cresol conversion but had no effect on product distribution.
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The HDO reaction mechanism could be explained with Remote Control model through the spillover hydrogen.
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NiS2 exhibited better promotional effect for the HDO activity of MoS2 than NiS and Ni3S4.