The amorphous NiB/Hβ catalyst was prepared and used for the isomerization of n-hexane first.
The acid properties of catalysts surface were mainly related to NiB loadings.
The sample with the maximum ratio of weak acid content to strong acid content has the highest yield.
The good dispersion of NiB nanoparticles was helpful for enhancing the synergistic effect.
The unique structure of BNiH probably existed in catalyst.