The “direct‿synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass
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- 作者：Nicolay Yu. Adonina ; b ; adonin@catalysis.ru" class="auth_mail" title="E-mail the corresponding author ; Sergey A. Prikhod&rsquo ; koa ; b ; Anton Yu. Shabalina ; Igor P. Prosvirina ; b ; Vladimir I. Zaikovskiia ; b ; Dmitry I. Kochubeya ; 1 ; Dmitry A. Zyuzina ; Valentin N. Parmona ; Evgeny A. Moninc ; Irina A. Bykovac ; Petr O. Martynovc ; Sergey L. Rusakovc ; Pavel A. Storozhenkoc
- 关键词：Direct synthesis ; Silicon ; Copper catalyst ; Active sites formation ; Silane ; Mechanism of active sites formation
- 刊名：Journal of Catalysis
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：338
- 期：Complete
- 页码：143-153
- 全文大小：2033 K
文摘
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The process of the copper-containing active sites formation was studied.
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Topochemical and heterogeneous chemical reactions take part in this process.
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A new mechanism of the activation of the contact mass was formulated.