Synthesis and characterization of metallatranes with phenyl substituents in atrane cage

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• 作者：Sergey S. Karlov ; Anastasia A. Selina ; Eleonora S. Chernyshova ; Yuri F. Oprunenko ; Alexei A. Merkulov ; Victor A. Tafeenko ; Andrei V. Churakov ; Judith A.K. Howard ; Galina S. Zaitseva
• 关键词：Trialkanolamine ligands ; Silatranes ; Boratranes ; NMR spectroscopy ; Crystal structure
• 刊名：Inorganica Chimica Acta
• 出版年：2007
• 出版时间：1 February 2007
• 年：2007
• 卷：360
• 期：2
• 页码：563-578
• 全文大小：525 K

文摘

A new series of mono- and diphenylsubstituted silatranes and boratranes N(CH₂CH₂O)₂(CHR³CR¹R²O)MZ (M = Si, Z = CH₂Cl, CCPh, H, OMenth, R¹, R², R³ = H, Ph; M = B, Z = nothing, R¹, R², R³ = H, Ph) have been synthesized. Both transalkoxylation and stepwise modification of a preformed metallatrane skeleton were used. The chloromethyl derivatives N(CH₂CH₂O)₂(CHRCHRO)SiCH₂Cl (R = H, Ph) react with tert-BuOK under intramolecular cycle expansion to give 1-tert-butoxy-2-carba-3-oxahomosilatranes N(CH₂CH₂O)(CH₂CH₂OCH₂)(CHRCHRO)SiO^tBu (R = H, Ph). The treatment of boratranes N(CH₂CH₂O)₂(CH₂CR¹R²O)B (R¹,R² = H, Ph) with triflic acid and trimethylsilyl triflate results in the products of electrophilic attack at the nitrogen atom. The molecular structures of four silatranes and one boratrane bearing phenyl groups in the atrane skeleton were determined by the X-ray structure analysis.