Hydrothermal synthesis and crystal structure of a mixed-valence Cu(I)/Cu(II) complex: [Cu₄(ophen)₄(mtp)] (Hophen=2-hydroxy-1,10′-phenanthroline, mtp=2-methyl-terephthalate

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• 作者：Feng ; Yuhua ; Han ; Zhangang ; Peng ; Jun ; Hao ; Xiangrong
• 关键词：Hydrothermal synthesis ; Crystal structure ; Mixed-valence copper complex
• 刊名：Journal of Molecular Structure
• 出版年：2005
• 出版时间：January 31, 2005
• 年：2005
• 卷：734
• 期：1-3
• 页码：171-176
• 全文大小：310 K

文摘

A new organic–inorganic hybrid mixed-valence Cu(I)/Cu(II) complex [Cu₄(ophen)₄(mtp)] (1) (Hophen=2-hydroxy-1,10′-phenanthroline, mtp=2-methyl-terephthalate acid) has been hydrothermally synthesized and characterized by XPS spectrum, FTIR spectrum and X-ray single-crystal diffraction. Compound 1 belongs to monoclinic system, space group P2(1)/n, a