Two {Mo36}-containing polymolybdates: Synthesis, crystal structures, and spectral characterizations
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- 作者：Zhangang Hana ; Wenbo Peia ; Jingli Xiea ; b ; Jingli.Xie@monash.edu ; Yang Zouc ; Xiao-Ming Rend
- 关键词：Polyoxometalate ; High-core cluster ; Coordination geometry ; Copper
- 刊名：Inorganic Chemistry Communications
- 出版年：2012
- 出版时间：February, 2012
- 年：2012
- 卷：16
- 期：Complete
- 页码：61-64
- 全文大小：1238 K
文摘
Two polyanion clusters [Mo36O108(NO)4(H2O)16]12 ?/sup> (rong class=""boldFont"">1 rong>) and [Mo36O112(H2O)16Cu0.5(H2O)2]7 ?/sup> (rong class=""boldFont"">2 rong>) were obtained through ¡®one-pot?reaction at ambient temperature and pressure. Both of rong class=""boldFont"">1 rong> and rong class=""boldFont"">2 rong> consist of {Mo36} anionic clusters. Interestingly, compound rong class=""boldFont"">2 rong> represents a case that the transitional metal copper is anchored into the framework of a giant {Mo36} isopolyanion.