Facile tunning the morphology and porosity of a superwetting conjugated microporous polymers

详细信息    查看全文

• 作者：Peng Mu^a ; Hanxue Sun^a ; Jiake Zang^a ; Zhaoqi Zhu^a ; Weidong Liang^a ; Fucheng Yu^a ; Lihua Chen^b ; ^{clh@xbmu.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; An Li^a ; ^{lian2010@lut.cn" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Conjugated microporous polymers ; Superhydrophobic ; Transparent ; Film ; Wettability
• 刊名：Reactive and Functional Polymers
• 出版年：2016
• 出版时间：September 2016
• 年：2016
• 卷：106
• 期：Complete
• 页码：105-111
• 全文大小：1705 K

文摘

A series of conjugated microporous polymers (CMPs) were synthesized via palladium-catalyzed Sonogashira-Hagihara crosscoupling polycondensation of N,N-bis(4-bromobenzyl)amine and 1,3,5-triethynylbenzene in different ternary solvents. The globular, tubular and amorphous CMP networks with different BET (Brunauer-Emmett-Teller) surface areas were obtained. Take advantages of superhydrophobic/oleophilic properties and microporous morphological structures of the resulting CMPs, a CMPs-based mesh film and a flexible, superhydrophobic, transparent CMPs-based film were prepared, which exhibit good oil/water separation performance and moderate transmittance. In addition, due to its abundant porous feature and unique chemistry nature of the as-prepared N-containing CMPs, the removal of the dyes from water and iodine from organic solvent have been investigated. The results show that the CMP-3 possesses the highest adsorption capacities of 269 mg g^− 1 for rhodamine B, 198 mg g^− 1 for methyl orange and 218 mg g^− 1 for iodine, respectively. This work provides a useful guidance for design and construction of porous CMPs materials for special applications.