The saturated adsorption capacity of alkylamines on Na + Bent decreases with the increasing of number of primary amine. The adsorption rate of alkylamines on Na + Bent increases with the increasing of number of primary amine. A flat-lying monolayer of alkylamine was intercalated and was firmly embedded in the interlayer space of Na + Bent. The inhibition performance of alkylamine on Na + Bent increases with the increasing of number of primary amine.