Mesophase pitch-based graphite fiber-reinforced acrylonitrile butadiene styrene resin composites with high thermal conductivity

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• 作者：Guanming Yuan^a ; ^b ; Xuanke Li^a ; ^b ; ^{xkli8524@sina.com" class="auth_mail" title="E-mail the corresponding author} ; Jing Yi^b ; Zhijun Dong^a ; ^b ; Aidan Westwood^c ; Baoliu Li^b ; Zhengwei Cui^b ; Ye Cong^b ; Jiang Zhang^b ; Yanjun Li^b
• 刊名：Carbon
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：95
• 期：Complete
• 页码：1007-1019
• 全文大小：3531 K

文摘

One-dimensional (1-D) and two-dimensional (2-D) mesophase pitch-based graphite fiber (MPGF)/acrylonitrile butadiene styrene (ABS) resin composites were prepared from unidirectionally arranged MPGF/ABS resin laminae by a hot-press method. The morphologies, optical texture and crystal structure of the MPGFs and their ABS resin composites were investigated. The influence of the volume fraction, diameter and graphitization temperature of the MPGFs and the composite architecture on the thermal properties of the composites was discussed. The thermal diffusivity and thermal conductivity of the resultant composites parallel to the longitudinal fiber direction increase markedly with the volume fraction, diameter and graphitization temperature of the fibers. The 1-D composite with a fiber volume fraction of 62% possesses a bulk density of 1.64 g/cm³ and shows a high thermal diffusivity of 372 mm²/s and a high thermal conductivity of 518 W/m K parallel to the longitudinal fiber direction at room temperature. The corresponding axial thermal conductivity of the fibers, graphitized at 2900 °C with a diameter of 50–55 μm, is estimated to be 825 W/m K. The 2-D composite filled with a high (54%) volume fraction of MPGFs also exhibits a high thermal conductivity in two directions (parallel to the longitudinal directions of the incorporated fibers).