The insertion of arynes into the O-H bond of aliphatic carboxylic acids

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• 作者：Chunxiao Wen ; Qian Chen ; ^{qianchen@gdut.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Zhenwen He ; Xinxing Yan ; Changyuan Zhang ; Zhiyun Du ; Kun Zhang ; ^{kzhang@gdut.edu.cn" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Arylation ; Insertion ; Aliphatic carboxylic acid ; Aryne
• 刊名：Tetrahedron Letters
• 出版年：2015
• 出版时间：30 September 2015
• 年：2015
• 卷：56
• 期：40
• 页码：5470-5473
• 全文大小：1847 K

文摘

The insertion of arynes into the O–H bond of aliphatic carboxylic acids promoted by sodium carboxylates is described. The reactions led to the formation of aryl carboxylates in good yields with good chemoselectivities under mild conditions.