Mild and efficient oxidation of phosphorus(III) compounds with Selectfluor
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- 作者：Qian Chen ; qianchen@gdut.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Jiekun Zeng&dagger ; ; Xinxing Yan&dagger ; ; Yulin Huang ; Zhiyun Du ; Kun Zhang ; Chunxiao Wen
- 关键词：Phosphines ; Phosphine oxides ; Oxidation ; Selectfluor
- 刊名：Tetrahedron Letters
- 出版年：2016
- 出版时间：27 July 2016
- 年：2016
- 卷：57
- 期：30
- 页码：3379-3381
- 全文大小：1141 K
文摘
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The oxidation of P(III) compounds with Selectfluor smoothly affords P(V) compounds in high yields.
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The reactions give tertiary phosphine oxides, phosphinates, and phosphonates at room temperature in minutes.
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The oxidation conditions are mild, user-friendly, and safe.