Iron(II) porphyrins induced conversion of nitrite into nitric oxide: A computational study
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- 作者：Ting Ting Zhang ; Yong Dong Liu ; ydliu@bjut.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Ru Gang Zhong
- 关键词：Iron(II) porphyrin ; DFT ; Nitrite ; Nitric oxide ; Proximal ligand
- 刊名：Journal of Inorganic Biochemistry
- 出版年：2015
- 出版时间：September 2015
- 年：2015
- 卷：150
- 期：Complete
- 页码：126-132
- 全文大小：827 K
文摘
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Nitrite reduction to NO mediated by iron(II) porphyrin was investigated by DFT method.
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The reduction reaction from N-nitro isomer is similar to that from O-nitrito isomer.
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Negative proximal ligands improve reactivities of N-nitro-iron(II) porphyrins.