Efficient conversion of carbohydrates into 5-hydroxymethylfurfural catalyzed by the chromium-exchanged montmorillonite K-10 clay

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• 作者：Zhongfeng Fang ; Bing Liu ; Jinju Luo ; Yongshen Ren ; Zehui Zhang
• 关键词：Carbohydrates ; 5-Hydroxymethylfurfural ; Dehydration ; Montmorillonite K-10 clays ; Green chemistry
• 刊名：Biomass and Bioenergy
• 出版年：January, 2014
• 年：2014
• 卷：60
• 期：Complete
• 页码：171-177
• 全文大小：589 K

文摘

An efficient process was developed for the conversion of carbohydrates into 5-hydroxymethylfurfural (HMF). A series of cation-exchanged montmorillonite K-10 clay were prepared as the heterogeneous catalysts for the conversion of carbohydrates into HMF, and chromium-exchanged K-10 clay (K-10 clay-Cr) was found to be the best catalyst for this transformation. A high HMF yield around 95% was obtained from the dehydration of fructose either in dimethyl sulfoxide (DMSO) or in [BMIM]Cl. Results demonstrated [BMIM]Cl was superior to DMSO for the conversion of glucose into HMF, and HMF yield of 51.9% was obtained from the dehydration of glucose at 120聽掳C after 2聽h in [BMIM]Cl. Furthermore, the developed methods were also effective for the synthesis of HMF from other carbohydrates. Particularly, a satisfied HMF yield of 48.7% could be obtained from the inedible and abundant cellulose. In addition, the catalyst was effectively recycled six times without significant loss of activity.