[PMo12O40]3 − anions as templates lead to a unique sandwich hybrid networks.
It is the first pure Mo-oxide-based polymers based on hexa-Mo unit's chains.
Compound 1 shows fluorescent properties in the solid state at room temperature.
Compound 1 displays good electrocatalytic activity on reduction of H2O2.
Compound 1 exhibits highly-efficient degradation ability for RhB under UV light.