Assembly of sandwich-type 3-D supramolecular coordination polymers based on hexa-molybdenum chain and {PMo12O40} heteropolyanion
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- 作者：Siqi Wana ; b ; Kai Yua ; b ; hlyukai188@163.com" class="auth_mail" title="E-mail the corresponding author ; Lu Wangc ; Zhanhua Sua ; b ; Baibin Zhoua ; b ; zhou_bai_bin@163.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Supramolecular ; [PMo12O40]3 ; &minus ; ; Coordination polymers ; Photocatalytic activity ; Electro-catalytic property
- 刊名：Inorganic Chemistry Communications
- 出版年：2015
- 出版时间：November 2015
- 年：2015
- 卷：61
- 期：Complete
- 页码：113-117
- 全文大小：1124 K
文摘
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[PMo12O40]3 − anions as templates lead to a unique sandwich hybrid networks.
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It is the first pure Mo-oxide-based polymers based on hexa-Mo unit's chains.
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Compound 1 shows fluorescent properties in the solid state at room temperature.
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Compound 1 displays good electrocatalytic activity on reduction of H2O2.
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Compound 1 exhibits highly-efficient degradation ability for RhB under UV light.