Organic-inorganic hybrid supramolecular assembly through the highest connectivity of a Wells-Dawson molybdoarsenate
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- 作者：Honghong Caia ; b ; Jinghua Lü ; a ; Kai Yua ; b ; hlyukai188@163.com" class="auth_mail" title="E-mail the corresponding author ; He Zhanga ; b ; Chunmei Wanga ; b ; Lu Wangc ; Baibin Zhoua ; b ; zhou_bai_bin@163.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Supramolecular ; As2Mo18O626 ; &minus ; ; Electrocatalysis ; Photocatalysis
- 刊名：Inorganic Chemistry Communications
- 出版年：2015
- 出版时间：December 2015
- 年：2015
- 卷：62
- 期：Complete
- 页码：24-28
- 全文大小：1099 K
文摘
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{As2Mo18} cluster attracts 14 bimyb ligands at its periphery via weak interaction.
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The ligands are further embraced by 22 Dawson anions to form 3D supramolecular nets.
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Compound 1 represents the highest connectivity of Dawson molybdoarsenate.
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Compound 1 shows bifunctional electrocatalytic behavior.
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Compound 1 exhibits highly-efficient degradation ability for MB under UV light.