This paper reports the growth and spectral properties of Er3+/Yb3+:LaCa4O(BO3)3. The Er3+/Yb3+:LaCa4O(BO3)3 crystal with diameter 30mm and length 40mm was obtained using the Czochralski method. The absorption and emission spectra of Er3+/Yb3+:LaCa4O(BO3)3 crystal have been investigated. The strong absorption band with absorption coefficient 13cm−1 at 900–1050nm was observed in Er0.05/Yb0.5:Ca4La0.45O(BO3)3 crystal. The emission band in 1510–1580 was observed, and its fluorescence lifetime is about 1.22ms at 300K.