Assembly of two-fold interpenetrated silver supramolecular coordination polymer using Keggin phosphotungstate template
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- 作者：He Zhanga ; b ; Kai Yua ; b ; hlyukai188@163.com" class="auth_mail ; Song Gaoc ; Chunmei Wanga ; b ; Chunxiao Wanga ; b ; Haiyan Wangc ; Baibin Zhoua ; b ; zhou_bai_bin@163.com" class="auth_mail
- 关键词：Organic&ndash ; inorganic hybrid ; Supramolecular materials ; Electrochemistry and electrocatalytic activity ; Fluorescent property
- 刊名：Inorganic Chemistry Communications
- 出版年：June 2014
- 年：2014
- 卷：44
- 期：Complete
- 页码：91-95
- 全文大小：1365 K
文摘
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Keggin-type [PW12O40]3 − anions as templates lead to an unusual hybrid material.
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It is the first two-fold interpenetrating supramolecular Keggin–POMMOF
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Helical hole constructed from alternate left- and right-handed chains is formed.
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Compound 1 shows fluorescent properties in the solid state at room temperature.
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Compound 1 displays good electrocatalytic activity on the reduction of nitrite.