Aluminium-assisted crystallization is used to grow single-crystalline SixGe1鈭抶 film epitaxially on Si substrate at a relatively low temperature (350-450 掳C). Investigation of the mechanism by which Al film causes epitaxial growth of SixGe1鈭抶 suggests a four-step growth process is involved. The composition of the SixGe1鈭抶 film can be controlled by the annealing conditions. This SixGe1鈭抶 film can be used as a buffer layer for the epitaxial growth of Ge on Si or as a virtual substrate for the fabrication of III-V devices.