Solvent-free oxidation of cyclohexane over covalently anchored transition-metal salicylaldimine complexes to α-zirconium phosphate using tert-butylhydroperoxide
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- 作者：Savita Khare ; kharesavita@rediffmail.com" class="auth_mail" title="E-mail the corresponding author ; Priti Shrivastava
- 关键词：α-Zirconium phosphate ; Salicylaldimine complex ; tert-Butylhydroperoxide ; Cyclohexane oxidation
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：411
- 期：Complete
- 页码：279-289
- 全文大小：1884 K
文摘
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New heterogeneous catalysts, α-ZrP.M(salicylaldimine) prepared by covalent bonding.
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Liquid phase oxidation of cyclohexane was studied using α-ZrP.M(salicylaldimine)/TBHP system.
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α-ZrP.Co(salicylaldimine) gave maximum 14.18% conversion with 92.33% selectivity (KA-oil).
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α-ZrP.Co(salicylaldimine) exhibit the excellent reusability.