2LiBH4-MgH2 nanoconfined into carbon aerogel scaffold impregnated with ZrCl4 for reversible hydrogen storage
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- 作者：Rapee Utkea ; rapee.g@sut.ac.th" class="auth_mail" title="E-mail the corresponding author ; Sophida Thiangviriyaa ; Payam Javadianc ; Torben R. Jensenc ; Chiara Milanesed ; Thomas Klassenb ; Martin Dornheimb
- 关键词：Nanostructures ; Metals ; Alloys ; Fourier transform infrared spectroscopy (FTIR) ; Powder diffraction
- 刊名：Materials Chemistry & Physics
- 出版年：2016
- 出版时间：1 February 2016
- 年：2016
- 卷：169
- 期：Complete
- 页码：136-141
- 全文大小：804 K
文摘
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Nanoconfined 2LiBH4–MgH2 in carbon aerogel scaffold (CAS) doped with ZrCl4.
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Studies of hydride: ZrCl4-doped CAS weight ratio affecting on H2 desorption.
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Reduction of H2 desorption temperature and faster kinetics after ZrCl4 doping.
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Up to 97 and 93% of theoretical H2 capacity released and reproduced, respectively.