In this paper, we classify locally projectively flat general 622451500114X&_mathId=si1.gif&_user=111111111&_pii=S092622451500114X&_rdoc=1&_issn=09262245&md5=7d8c9062a42d4ab098f104a4ba4225d4" title="Click to view the MathML source">(α,β)-metrics 622451500114X&_mathId=si159.gif&_user=111111111&_pii=S092622451500114X&_rdoc=1&_issn=09262245&md5=c4b66b2421189b3dd22e190f9d256222">622451500114X-si159.gif"> on an 622451500114X&_mathId=si160.gif&_user=111111111&_pii=S092622451500114X&_rdoc=1&_issn=09262245&md5=1b128c77f224eef1f2472027ac1a38ed" title="Click to view the MathML source">n(≥3)-dimensional manifold if α is of constant sectional curvature and 622451500114X&_mathId=si167.gif&_user=111111111&_pii=S092622451500114X&_rdoc=1&_issn=09262245&md5=0e01095735c734a5fb0a91710259b337" title="Click to view the MathML source">ϕ1≠0. Furthermore, we find equations to characterize this class of metrics with constant flag curvature and determine their local structures.