Catalytic oxidation of 2,4,6-tribromophenol using iron(III) complexes with imidazole, pyrazole, triazine and pyridine ligands
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- 作者：Mami Igarashia ; Qianqian Zhua ; Masahide Sasakib ; Ritsu Kodamaa ; Kohki Odaa ; Masami Fukushimaa ; m-fukush@eng.hokudai.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Non-heme ; Terpyridine ; Catalytic oxidation ; 2 ; 4 ; 6-Tribromophenol ; Humic acid
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：413
- 期：Complete
- 页码：100-106
- 全文大小：1082 K
文摘
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Catalytic oxidation of TrBP was tested by using five non-heme Fe(III) complexes.
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The mer-[FeCl3(terpy)] had the highest capability to TrBP degradation with KHSO5.
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DBQ was detected as a major byproduct and further degraded to organic acids.
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15% of the degraded TrBP was mineralized to CO2 in mer-[FeCl3(terpy)]/KHSO5 system.
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The mer-[FeCl3(terpy)] was activated by forming peroxide complex with oxygen donor.