Homogeneous oxidation of alkanes: Role of rhodium-alkyl complexes

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• 作者：E.G. Chepaikin^a ; ^{echep@ism.ac.ru} ; ^{grig@ism.ac.ru} ; A.P. Bezruchenko^a ; G.N. Menchikova^a ; А.Е. Gekhman^b
• 关键词：Alkanes ; Oxidation ; Homogeneous catalysis ; Rh&ndash ; alkyl bond
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：389-392
• 全文大小：774 K
• 卷排序：426

文摘

Induction period in oxidation of CH4 and C3H8. Formation of CH3Cl, n-C3H7Cl, i-C3H7Cl, and C4H9Br. Positional selectivity in oxidation of propane. Formation of Rh–alkyl intermediates. Synthesis of acetic acid from CH4, CO, and O2.