Reactivity of nitrogen atoms in adenine and (Ade)2Cu complexes towards ribose and 2-furanmethanol: Formation of adenosine and kinetin
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- 作者：Ossanna Nashalian ; Varoujan A. Yaylayan ; varoujan.yaylayan@mcgill.ca" class="auth_mail" title="E-mail the corresponding author
- 关键词：Adenine ; Reducing sugars ; 2-Furanmethanol ; Kinetin ; Adenosine ; (Ade)2Cu complexes ; Amadori product ; Maillard reaction
- 刊名：Food Chemistry
- 出版年：2017
- 出版时间：15 January 2017
- 年：2017
- 卷：215
- 期：Complete
- 页码：463-469
- 全文大小：1125 K
文摘
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The N6 and N9 of adenine can selectively react with sugars and 2-furanmethanol.
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Adenine copper complexes activate the N9 of adenine and form di-glycated adenine.
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Di-ribosylated adenine and kinetin were formed for the first time from adenine.
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Reaction of adenine with 2-furanmethanol generated kinetin and its isomer.
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Reaction of adenosine with 2-furanmethanol generated kinetin riboside.