Reactions of cyclopalladated complexes with HPPh₂ resulting in ligand phosphination

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• 作者：Jonathan E. Kukowski ; Valeria A. Stepanova¹ ; Irina P. Smoliakova ; ^{irina.smoliakova@UND.edu}
• 关键词：Cyclopalladated complex ; Reactions at the CPd bond ; Phosphination ; Diphenylphosphine ; CH functionalization via palladacycles
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：830
• 期：Complete
• 页码：155-166
• 全文大小：995 K
• 卷排序：830

文摘

sp3CP bonds have been formed by reaction of cyclopalladated complexes with HPPh2. Two new types of rare terminal phosphido Pd(II) complexes have been isolated. Key intermediates appear to be Pd(II) species with a terminal PPh2 ligand.