Micellar effect on hetero-aromatic nitrogen base promoted chromic acid oxidation of 1.3-propanediol in aqueous media at room temperature

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• 作者：Susanta Malik^a ; Debabrata Saha^a ; ^b ; Monohar Hossain Mondal^a ; ^c ; Pintu Sar^a ; Aniruddha Ghosh^a ; Kalachand Mahali^d ; Bidyut Saha^a ; ^{b_saha31@rediffmail.com}
• 关键词：1 ; 3-Propanediol ; 3-Hydroxy propionaldehyde ; 2.3-Pyridine dicarboxylic acid ; TX-100 ; nanoreactor
• 刊名：Journal of Molecular Liquids
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：225
• 期：Complete
• 页码：207-216
• 全文大小：1996 K
• 卷排序：225

文摘

The total oxidation reaction has been carried out in aqueous micellar media. Oxidation of 1.3-propanediol totally transfers the highly toxic Cr(VI) into less toxic Cr(III). Promoters such as PA, bipy, phen and 2.3-diPA used to accelerate the reaction rate in presence and absence of surfactant A combination of TX-100 and Phen is the best choice for the oxidation reaction.