New trans-dichloropalladium(II) complexes of 7-azaindole: Crystal and molecular structures, FT-IR, FT-Raman and DFT studies
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- 作者：Barbara Morzyk-Ociepaa ; bmorzyk-ociepa@o2.pl" class="auth_mail" title="E-mail the corresponding author ; Karolina Dysza ; Ilona Turowska-Tyrkb ; Danuta Michalskab
- 关键词：Trans-dichloropalladium(II) ; 7-azaindole complexes ; Raman and IR spectra ; Crystal structure ; NBO calculations
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：5 January 2016
- 年：2016
- 卷：1103
- 期：Complete
- 页码：202-211
- 全文大小：1396 K
文摘
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New palladium complexes with 7-azaindole (7AI) have been synthesized.
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The trans structure was confirmed by single crystal XRD, FT-IR, FT-Raman studies.
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A detailed interpretation of the IR and Raman spectra is reported.
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Controversial assignment of the Pd–N stretching vibrations is elucidated.
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NBO analysis reveals strong electron delocalization in the complex.