pH-Dependent two novel heteronuclear Cu(II)/Sr(II) coordination polymers constructed from 1,3,5-benzenetricarboxylic acid: Synthesis, crystal structures and properties
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- 作者：Qiao-Zhen Suna ; Yi-Biao Yina ; Jun-Qiao Pana ; Li-Yuan Chaib ; c ; Nan Sua ; Hui Liub ; c ; leolau@csu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Yi-Lin Zhaoa ; Xing-Tao Liua
- 关键词：Heteronuclear coordination polymers ; X-ray crystallography ; Topology ; pH dependence
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：15 February 2016
- 年：2016
- 卷：1106
- 期：Complete
- 页码：64-69
- 全文大小：1495 K
文摘
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Two pH-dependent heteronuclear coordination polymers using 1,3,5-benzenetricarboxyl acid ligand have been synthesized.
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5">The ligand in compound 2 is oxidized into 2-hydroxytrimesic acid and shows totally different 3D structure compared with 1.
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The structures of the compounds are determined by X-ray study.
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5">The coordination polymers are characterized by IR, luminescence and TGA techniques.