Chemical physics behind formation of effective and selective non-covalent interaction between fullerenes (C60 and C70) and a designed chiral monoporphyrin in solution
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- 作者：Anamika Raya ; Shrabanti Banerjeeb ; Ajoy K. Bauric ; Sumanta Bhattacharyaa ; sum_9974@rediffmail.com" class="auth_mail" title="E-mail the corresponding author
- 刊名：Chemical Physics Letters
- 出版年：2016
- 出版时间：16 February 2016
- 年：2016
- 卷：646
- 期：Complete
- 页码：119-124
- 全文大小：1173 K
文摘
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Non-covalent interaction of fullerenes with a chiral monoporphyrin (1) is studied in solution.
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C70 shows 10 times selectivity of binding towards 1 compared to C60.
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Static quenching mechanism is responsible behind photoexcited decay of 1.
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DFT calculations establish side-on binding motif of C70 towards 1 during complexation.