Dioxygen activation chemistry by synthetic mononuclear nonheme iron, copper and chromium complexes

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• 作者：Seungwoo Hong^a ; Yong-Min Lee^a ; Kallol Ray^b ; ^{kallol.ray@chemie.hu-berlin.de} ; Wonwoo Nam^a ; ^{wwnam@ewha.ac.kr}
• 关键词：Metalloenzymes ; Biomimetics ; Dioxygen activation ; Metal-oxygen intermediate ; Nonheme models
• 刊名：Coordination Chemistry Reviews
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：334
• 期：Complete
• 页码：25-42
• 全文大小：3693 K
• 卷排序：334

文摘

Recent advances in the O2-activation by biomimetic complexes are described. Synthetic and mechanistic developments of O2-activation processes are presented. Versatility of metal-oxygen species in various reactions is discussed.