First study of the B<sub>1gsub> buckling phonon mode in optimally doped, de-twinned, YBa<sub>2sub>Cu<sub>3sub>O<sub>7−sub><sub>δsub>
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We have measured the buckling, B<sub>1gsub>, phonon mode of optimally doped, de-twinned, YBa<sub>2sub>Cu<sub>3sub>O<sub>7−sub><sub>δsub> using inelastic X-ray scattering (IXS) at BL35XU of SPring-8. Measurements of this mode, which has atomic motion transverse to the Cu–O planes, serve to demonstrate some of the advantages of the unique two-dimensional (2-D) analyzer array at BL35. Analysis based on fitting the entire spectra simultaneously at 10 and 100 K shows that the buckling mode is rather broad in the middle of the zone (near (0.3 0 0)). We see a consistent softening of the mode at 10 K as compared to 100 K for all measured wave-vectors (h 0 0), and a q-dependent softening as zone center is approached.

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