CuHCF NPs were surface-capped with [FeII(CN)6]4− to be well water-dispersed as an ink.
CuHCF film can be simply and uniformly coated on electrodes of any size for column study.
A novel battery-type column using sandwiched NPs film of CuHCF was applied for sequential removal of Cs.
Cs separation can be simply controlled by modulating the potential of CuHCF film.
CuHCF NPs film is stable, even after 100 cycles of Cs adsorption and desorption.