New insights on the electrochemical oxidation of ethanol on carbon-supported Pt electrode by a novel electrochemical mass spectrometry configuration
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- 作者：Olmedo Guillé ; n-Villafuerte ; Gonzalo Garcí ; a ; ggarcia@ull.edu.es" class="auth_mail" title="E-mail the corresponding author ; Ma Carmen Aré ; valo ; José ; Luis Rodrí ; guez ; Elena Pastor ; epastor@ull.edu.es" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ethanol electrooxidation ; Methane ; EC-MS ; Carbon dioxide ; Fuel cells
- 刊名：Electrochemistry Communications
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：63
- 期：Complete
- 页码：48-51
- 全文大小：401 K
文摘
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A new configuration of an electrochemical mass spectrometry (EC-MS) was developed.
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The electrooxidation of ethanol on technical carbon-supported Pt (Pt/C) catalyst was studied.
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Methane formation during the positive sweep potential is reported for the first time.
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A complete reaction mechanism for the ethanol oxidation on Pt/C was carried out.