Synthesis, characterization and electrical studies of solid polymer electrolyte (1 − x) PANI-KAg₄I₅·xAl₂O₃

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• 作者：Sakshi Singh ; Rafiuddin ; ^{rafiuddin.chem11@gmail.com} ; ^{rafi_amu@yahoo.co.in}
• 关键词：Polymer solid electrolytes ; XRD ; SEM ; Electrical conductivity ; Impedance spectroscopy
• 刊名：Journal of Industrial and Engineering Chemistry
• 出版年：2017
• 出版时间：25 January 2017
• 年：2017
• 卷：45
• 期：Complete
• 页码：85-91
• 全文大小：1445 K
• 卷排序：45

文摘

(1 − x) PANI-KAg4I5·xAl2O3 is prepared by solid state reaction method. Electrical conductivity varies with the concentration of alumina. The composition x = 0.4 is found to have the maximum conductivity and minimum activation energy, i.e. 0.14 eV. The maximum conductivity is in the order of 10−1 S cm−1. Structure of the composite is confirmed by XRD, DTA, SEM and impedance spectroscopy.