Catalytic oxidation of α-alkenes with hydrogen peroxide to carboxylic acids in the presence of peroxopolyoxotungstate complexes
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- 作者：Z.P. Pai ; zpai@catalysis.ru" class="auth_mail" title="E-mail the corresponding author ; N.V. Selivanova ; P.V. Oleneva ; P.V. Berdnikova ; A.M. Beskopyl'nyi
- 关键词：Phase-transfer catalysis ; Alpha-alkenes ; Carboxylic acids ; Peroxotungstate complexes ; Quaternary ammonium cations
- 刊名：Catalysis Communications
- 出版年：2017
- 出版时间：5 January 2017
- 年：2017
- 卷：88
- 期：Complete
- 页码：45-49
- 全文大小：817 K
文摘
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α-Alkenes were oxidized in a two-phase system by H2O2 in the presence of metal complex catalysts.
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Carboxylic acids (С7, С9 and С11) were found to form with high yields (86–97%).
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This approach as for carboxylic acids synthesis may be of interest for “green chemistry” processes.