Synthesis, structural characterization, and evaluation of biological activity of organotin(IV) complexes with 2-hydroxy-5-methoxybenzaldehyde-N(4)-methylthiosemicarbazone
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- 作者：M.A. Salama ; salambpx@yahoo.com" class="auth_mail" title="E-mail the corresponding author ; salam@bapex.com.bd" class="auth_mail" title="E-mail the corresponding author ; Mouayed A. Husseinb ; Irmawati Ramlic ; Md. Saiful Islamc
- 关键词：2-Hydroxy-5-methoxybenzaldehyde-N(4)-methylthiosemicarbazone ; Organotin(IV) complexes ; Spectral characterization ; Crystal structure ; Cytotoxic activity
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 July 2016
- 年：2016
- 卷：813
- 期：Complete
- 页码：71-77
- 全文大小：1095 K
文摘
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Organotin(IV) complexes of 2-hydroxy-5-methoxybenzaldehyde-N(4)-methylthiosemicarbazone are synthesized.
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Newly synthesized compounds are characterized by various spectroscopic methods.
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We report the molecular structures of the ligand and its diphenyltin(IV) complex.
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X-ray crystal studies indicated tin(IV) atom is five-coordinated and adopts a distorted trigonal bipyramidal geometry.
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Organotin(IV) complexes can be considered as a potential anticancer agents.